Hi Jack,

The two Na D lines are from the two different spin levels.  (3s  to 3p1/2 and 3p3/2 in absorption) There probably is Zeeman splitting of the lines as well but this will be very small in the solar magnetic field.

Cheers

Robin

Hi both,

Robin is correct, the splitting comes from the two 3p levels, which would be degenerate (i.e. no doublet) if not for the spin-orbit coupling - a sort of internal Zeeman effect from the magnetic field induced by the orbiting electron. This splits the levels and creates the doublet. If we apply a weak magnetic field (similar in size to the spin-orbit bit) we'll get Zeeman splitting of these levels and end up in turn with 10 lines (5 from each line of the doublet)

The Na triplet is more complicated, but I think this comes from a similar 4s -> 3d transition, and selection rules exclude some of the 5 sublevels of the 3d orbital, giving a triplet - I'm slightly less clear on this one.

Regards,

Tom

If you go on the NIST spectral data base and look at the  relevant lines it shows you the transitions involved.

As above the splitting is due to the spin orbit coupling of the magnetic moments.

Regards Andrew 

It might be worth pointing out that the H alpha line is made up of 7 components with two being significantly stronger than the others. The splitting is small withthe largest spin orbit coupling split in the 2p level (J = 3/2 ,1/2) 

The theory of the spectrum of the Hydrogen atom traces the development of the quantum theory of light and matter. From the Bohr model where all the lines are degenerate in the prime quantum number  (as the are in the Schrodinger model) through the development of Sommerfeld and Schrodinger to the relativistic theory of Dirac, Darwin, Lamb and on to QED for which Shin'ichirō Tomonaga, Julian Schwinger and Richard Feynman got the Nobel prize building on the work of many others, where they are all split apart.